Analysis of sulfur in modern sediments by Lise Pharand

Cover of: Analysis of sulfur in modern sediments | Lise Pharand

Published by Laurentian University in Sudbury, Ont .

Written in English

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StatementLise Pharand ; supervisor: N. Belzile.
The Physical Object
Pagination32 l. :
Number of Pages32
ID Numbers
Open LibraryOL22160778M

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Sediments is another source of sulphate. Common rock-forming silicate minerals, including feldspar, mica and pyroxene, also contain significant amounts of sulphur, typically in the range 20 to mg kg Sodalite commonly contains S up to percentage levels, and non-silicates, such as apatite, can contain up to mg kg-1 S (Wedepohl ).

Assumptions commonly made during analysis of the amount of monosulfides [acid-volatile sulfides (AVS)] and disulfides in modern sediments, may not be valid for ancient sedimentary rocks.

Analysis of sulfur in modern sediments book is known that ferric iron can oxidize H2S during AVS analysis unless a reducing agent such as stannous chloride is added to the treatment. In addition, some monosulfides such as greigite and pyrrhotite. Analysis of sulfur in soil, plant and sediment materials: Sample handling and use of an automated analyzer December Soil Biology and Biochemistry 21(1) Elemental sulfur occurs naturally in marine and limnic sediments.

Elemental sulfur, brought in solution in aqueous media by using organic solvents such as methanol as carrier solvent, was toxic in. Assumptions commonly made during analysis of the amount of monosulfides [acid-volatile sulfides (AVS)] and disulfides in modern sediments, may not be valid for ancient sedimentary rocks.

It is known that ferric iron can oxidize H 2 S during AVS analysis unless a reducing agent such as stannous chloride is added to the by: The formation processes of metal sulfides in sediments, especially iron sulfides, have been the subjects of Analysis of sulfur in modern sediments book scientific research because of linkages to the global biogeochemical cycles of iron, sulfur, carbon, and oxygen.

ChemicalGeology, () 83 Elsevier Science Publishers B.V., Amsterdam [AL] The analysis of forms of sulfur in ancient sediments and sedimentary rocks: comments and cautions Cynthia A. Rice, Michele L. Tuttle and Richard L. Reynolds U.S. Geological Surve_v, BoxMS. The use of chromium reduction in the analysis of reduced inorganic sulfur in sediments and shales.

Chem. Geol., A sulfur analysis scheme employing the use of chromium reduction for the determination of reduced inorganic sulfur compounds (pyrite + elemental sulfur + acid volatile monosulfides) in modern sediments and shales is.

The material is grouped under major subject headings called books and further subdivided into sections and chapters; Section C of Book 5 is on sediment analysis.

The unit of publication, the chapter, is limited to a narrow-field of subject matter. Sulfur-TOC in modern sediments: (a) S and (b) S/TOC versus watermass salinity, and (c) S versus TOC.

In (c), a S/TOC threshold of is highly effective at differentiating freshwater versus brackish/marine facies; the latter facies exhibit substantial overlap is the range of –, although nearly all samples with S/TOC > are marine.

Mohammadpour Reza Chan Ngai Weng "Stable channel analysis with sediment transport for rivers in Malaysia: A case study of the Muda, Kurau, and Langat rivers. " International Journal of Sediment Research / Online publication date: March Pähtz Thomas Durán Orencio " Unification of Aeolian and Fluvial Sediment.

presented applications include the sulfur isotope analysis of extremely low amounts of sulfate from saline water, the conversion of radiolabeled sulfate into sulfide, the extraction of refractory sulfur from marine sediments, and the use of this method to assess sulfur cycling in Aarhus Bay sediments.

A sulfur analysis scheme employing the use of chromium reduction for the determination of reduced inorganic sulfur compounds (pyrite + elemental sulfur + acid volatile monosulfides) in modern sediments and shales is presented.

Purchase Sulfidic Sediments and Sedimentary Rocks, Volume 65 - 1st Edition. Print Book & E-Book. ISBN  Understanding the sulfur cycle mechanism and controlling the sulfur cycle in sediment biofilm are essential to solve these problems. In this review, the reaction mechanisms of the sulfur cycle in sediment biofilm in sewer systems revealed by using in situ microelectrode measurements and molecular biological technologies are summarized.

This attractive volume presents the history, characteristics, and uses for that vibrant yellow element, sulfur. Commercial sulfuric acid production from the early 16th century until today is reviewed, spanning the Ancient and Renaissance periods, the Industrial Age (to which sulfur was vitally important), and the Sulfur War of The book introduces "the Sulfur Age" and the processes of.

The isotopic information supports earlier suggestions that pyrite in the modern sediments of the Black Sea forms mainly in the water column, with only minor amounts forming in the sediment. Sulfur isotope analysis of microcrystalline iron sulfides using secondary ion mass spectrometry imaging: Extracting local paleo‐environmental information from modern and ancient sediments.

Roger N. Bryant. Corresponding Author. E-mail address: [email protected] Together, OSM represent the second most important reduced sulfur pool in marine sediment environments, accounting for up to 35–80% of the reduced sulfur (Bruchert and Pratt, ; Passier et al., ).

Sulfonated organics may comprise 20–40% of the organo‐sulfur in marine sediments (Vairavamurthy et al., ). The data obtained on pyrite sulfur in sediments and sulfate sulfur in pore waters, as well as on the isotope composition of the sulfur, are shown in Tables 1 to 4 and Figures 2 to 5.

In plotting the graphs, we also used the results of C org determinations performed on board the Glomar Challenger. Sulfide and Sulfur Sediments The content of. Elemental sulfur was produced by the reaction between H2S and SO2, while anoxygenic photosynthesis may have provided the sulfate which removed oceanic ferrous iron by its precipitation as sulfide into sediments.

Hence, the sulfur cycle participation in life evolution comes from ancient anoxygenic elemental sulfur reduction generating. A number of sulfur organic compounds present in nineteen bottom sediment samples from the Eastern Gulf of Finland (EGF) were characterized by high performance gas chromatography connected to low.

The formation and pathways of thiosulfate (S 2 O 3 2−) in anoxic sediment were studied in the Odder River and Brabrand Lake, ‐course experiments were done in slurries with four 35 S tracers: SO 4 2−, H 2 S, and S 2 O 3 2− with either the inner (oxidized) or the outer (reduced) S atom labeled.

The two sediments gave similar results. Of all the S 2 O 3 2− consumed in. Volatile organic sulfur compounds (VOSCs) link the atmospheric, marine, and terrestrial sulfur cycles in marine and marginal marine environments.

Despite the important role VOSCs play in global biogeochemical sulfur cycling, less is known about how the local geochemical conditions influence production and consumption of VOSCs. The analysis of the quantity and sulfur isotope composition of acid-volatile sulfur and chromium-reducible sulfur (CRS) in sediments and rocks (and references therein) is common to many sulfur geochemistry studies.

The STRIP distillation can be used for the determination of the sulfur content and isotope composition of bulk sediment and rock.

ies demonstrated that sediment sulfur con- centrations sed in areas with very high atmospheric sulfate deposition (> 50 kg ha-i yr-I) (Nriagu and Soon ; Gib- lin et al.

; Carignan and Tessier ), analysis of four cores from Little Rock Lake show consistent increases in sediment sulfur. Reduced sulfur in euxinic sediments of the Cariaco Basin: sulfur isotope constraints on organic sulfur formation Josef P.

Wernea,b,*, Timothy W. Lyonsc, David J. Hollandera,1, Michael J. Formoloc, Jaap S. Sinninghe Damste´b aDepartment of Geological Sciences, Northwestern University, Evanston, ILUSA bDepartment of Marine Biogeochemistry and Toxicology, Netherlands Institute for Sea.

Sulfur isotope analysis of microcrystalline iron sulfides using secondary ion mass spectrometry imaging: Extracting local paleo-environmental information from modern and ancient sediments.

ever, sulfur isotopes are conserved during sulfate re-duction and sulfide reoxidation in organic-rich sediments.

Recent work has suggested that the sulfate cycle may have varied considerably more through Earth history than was previously assumed due to the impor-tance of this sulfur cycling in organic-rich sediments [4].

The XRF method depends on fundamental principles that are common to several other instrumental methods involving interactions between electron beams and x-rays with samples, including: X-ray spectroscopy (e.g., SEM - EDS), X-ray diffraction (), and wavelength dispersive spectroscopy (microprobe WDS).

The analysis of major and trace elements in geological materials by x-ray. Sediment samples were taken from the cores using cut syringes at intervals of 5 cm from the surface to a depth of 20 cm. Two 5 ml sediment samples were taken at each depth in each core—one for headspace VOSC analysis and one for DMSP analysis.

The sediment samples were injected and crimp sealed into ml nitrogen‐flushed glass vials. Sulfur isotope analysis of microcrystalline iron sulfides using secondary ion mass spectrometry imaging: Extracting local paleo-environmental information from modern and ancient sediments. Bryant RN(1), Jones C(1), Raven MR(1)(2), Gomes ML(3), Berelson WM(4), Bradley AS(1), Fike.

Get this from a library. Sulfidic sediments and sedimentary rocks. [David T Rickard] -- "The geochemistry and chemistry of sulfur, iron and iron sulfides in sedimentary systems is reviewed.

Sulfur microbiology is described and the microbial ecology of sulfidic sediments is discussed. Sulfur as an Internal Standard for the Quantitation of Environmental Sulrur by Combined Gas Chromatography -Mass Spectrometry. Analytical Letters12 (7), DOI: / M.

Sammut, G. Nickless. Petroleum hydrocarbons in marine sediments and animals from the island of malta. Analysis of 3-m sediment cores revealed that profiles of carbon (C), sulfur (S), and iron (Fe) varied with relative distance from marine and terrestrial sediment sources in Tomales Bay California.

PRINCIPLE OF THE GC-COUPLED SULFUR CHEMILUMINESCENCE METHOD. Analysis of H 2 S levels in biological samples using GC with sulfur chemiluminescence detection relies on the equilibration of H 2 S between the liquid sample and gas phases in a hermetically sealed sample chamber.

H 2 S present in the gas phase is measured following GC separation from other sulfur compounds and. Our SEM images showed the framboidal morphology in the riverbed sediment but not in the mud pool sediment, and the X‐ray diffraction analysis clearly showed that both the sediments contained iron disulfide (FeS 2) as pyrite and as its dimorph, marcasite (Figures 6 and 7), indicating that FeS 2 was a likely electron donor for sulfur.

Mass-independent fractionation (MIF) of sulfur isotopes has been reported in sediments of Archean and Early Proterozoic Age (> Ga) but not in younger rocks. The only fractionation mechanism that is consistent with the data on all four sulfur isotopes involves atmospheric photochemical reactions such as SO 2 photolysis.

About this book. Stromatolites: Interaction of Microbes with Sediments provides an overview and latest information about the formation of Stromatolites as a result of interaction of microbes with sediments.

Eighty-three expert scientists from twenty-seven countries present the chapters in Stromatolites: Interaction of Microbes with Sediments which have been reviewed by thirty four referees. INTRODUCTION. Microbial sulfate reduction (MSR) is a process of anaerobic respiration that utilizes sulfate as an electron acceptor.

This process remineralizes organic carbon in anoxic marine sediments and is the main driver of the global biogeochemical cycle of sulfur (8, 13).Of the four stable isotopes of sulfur in nature (32 S, 33 S, 34 S, and 36 S), MSR preferentially utilizes lighter S.

3. Soil analysis 17 Available nutrient content of soils 17 Soil sampling 17 Dispatch of soil samples to the laboratory 20 Preparation of soil samples for analysis 20 Analytical methods 22 4. Plant analysis 77 Sample collection and preparation for analysis 80 Analytical methods 81 5.

Water analysis 91 Important characteristics of irrigation water   A bushel of corn contains lb. of sulfur in the grain and lb. in the stalk, for a total of lb. "So bu. corn removes 34 lb.

of sulfur, or lb. of sulfate [the form taken up by. Modern δ in has been estimated at between 3 and 8% (15, 16), and ref. 12 has used a value of 8% to calculate f py from the isotope histories of pyrite and seawater sulfate through time.

These results are reproduced in Fig. 1 (δ in-constrained).The range in results accommodates variability imposed by assuming a dynamic mass balance which allows changes in M sw through time (in other words.

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